I'm still not quite following. The volume setting just determines the signal gain. Are we saying that at a digital input level of 0dB (i.e. full volume), the pre-out voltage will be 1.5V when the volume control is set at "80" (="0")?
yes I believe that's the case, though I think @amirm can confirm he tests at 0dbFS? Also, I guess any gain applied by Audyssey to your speaker channels would eat into this as well so f ex if a channel is set at +6dB then 1.5V is at -6dB(whatever the linear scale setting equivalent of that is).
This would all be pretty easy to double check with REW and a multimeter of course...I rarely exceed -10dB and all my channel gains are well below +5 so I haven't tried.
Also that is all worst case, assuming the tests are at 0dbFS, as all content is explicitly mastered to never reach that, as far as I understand.