Microphones are better at this than humans.
I wouldn't be so sure. In particular, humans can perceive side reflections better than a single microphone can because we have two ears and our auditory system is capable of interpreting the delay and level difference between them. Of course, it should be theoretically possible to do the same using two microphones, but it's non-trivial from a signal processing perspective and I don't know anyone who does measurements that way.
This is the main reason why people like @Floyd Toole warn against reading too much in "in-situ" frequency response measurements done with a microphone in a room, especially in medium and high frequencies.
I do agree that for most other kinds of measurements, an appropriate microphone and/or audio analyzer can be way more accurate and sensitive than any human "golden ear" could ever hope to be.